• Mikhail Aleksandrovich Vyboishchik Togliatti State University
  • Andrey Vladislavovich Ioffe LLC “IT-Service”
Keywords: oil-field environment, oil-and-gas pipeline tubes, oil-well tubing, ase steel, corrosion resistance, strength, plasticity, crack resistance, hydrogen cracking, carbon dioxide corrosion, structural condition, heat treatment, thermomechanical treatment


The authors carried out the survey of the crashworthiness of the oil-field and transportation equipment and noted the significant (by times, and sometimes dozens of times) exceeding of the allowable reliability index of the pipeline systems according to the values of the specific failure rate (item/km/year). It is shown that the main reason for pipe degradation and fracture is the internal corrosion which, depending on the composition of produced fluids, is manifested by one predominant type or the combination of several types of stress-corrosion fracture: hydrogen cracking, sulfide stress corrosion cracking, carbon dioxide, sulfide, and bacterial corrosion. Based on the generalization and systematization of the results of numerous research and applied works on the development and utilization of new pipe steels with the increased strength and corrosion resistance, the main scientific ideas of the formation of steel corrosion resistance in the highly aggressive oil-field fluids are proposed. The authors developed the methodology and offered the sequence of measures (algorithm) to solve set problems on the development of steels for production of oil pipes with higher mechanical properties and the resistance to stress-corrosion fracture. A list of necessary research, tests, and requirements to the product quality is defined. The authors proved the rationality of used approaches, methods, and decisions on the alloying, microalloying, modifying, and selection of the structural condition of the developed steels and on the technology of pipe production. The paper presents the examples of the development of new steels with the increased strength and corrosion resistance and, consequently, for the efficient solution of issues of the improvement of the performance characteristics of oil-and-gas pipeline and oil-well tubes.  

Author Biographies

Mikhail Aleksandrovich Vyboishchik, Togliatti State University

Doctor of Science (Physics and Mathematics), Professor, professor of Chair “Nanotechnologies, Materials Science and Mechanics”

Andrey Vladislavovich Ioffe, LLC “IT-Service”

PhD (Engineering), Head of Department of Materials Science


Zavyalov V.V. Problemy ekspluatatsionnoy nadezhnosti truboprovodov na pozdney stadia razrabotki mestorozhdeniy [The problems of functional reliability of pipelines at the late stage of oil fields development]. Moscow, VNIIO-ENG Publ., 2005. 322 p.

Knyazkin S.A. Vybor sostava i struktury stali dlya izgotovleniya nasosno-kompressornykh trub s povyshennymi ekspluatatsionnymi kharakteristikami. Diss. kand. tekhn. nauk. [The selection of composition and structure of steel for production of oil-well pipes with the improved functional characteristics]. Penza, 2013. 165 p.

Ioffe A.V., Tetyueva T.V., Knyaz’kin S.A., Zyryanov A.O., Vyboishchik M.A. Corrosion-mechanical fracture of tubing from carbon and alloy steels operating in environments containing hydrogen sulfide. Metal science and heat treatment, 2013, vol. 54, no. 9-10, pp. 492–497.

Nagumo M. Fundamentals of hydrogen embrittlement. Singapore, SpringerNature, 2016. 241 p.

Lynch S.P. Hydrogen embrittlement phenomena and mechanisms. Corrosion Reviews, 2012, vol. 30, no. 3-4, pp. 105–123.

Robertson I.M., Sofronis P., Nagao A., Martin M.L., Wang S., Gross D.W., Nygren K.E. Hydrogen embrittlement understood. Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science, 2015, vol. 46, no. 6, pp. 2323–2341.

Markin A.N., Nizamov R.E. СО2-korroziya neftepromyslovogo oborudovaniya [СО2-corrosion of oilfield equipment]. Moscow, VNIIOENG Publ., 2003. 188 p.

Sun J., Sun C., Wang Y. Effect of Cr content on the electrochemical behavior of low-chromium X65 steel in CO2 environment. International Journal of Electrochemical Science, 2016, vol. 11, no. 10, pp. 8599–8611.

Ko M., Ingham B., Laycock N., Williams D.E. In situ synchrotron X-ray diffraction study of the effect of chromium additions to the steel and solution on CO2 corrosion of pipeline steels. Corrosion Science, 2014, vol. 80, pp. 237–246.

Sun J., Sun C., Lin X., Cheng X. Effect of chromium on corrosion behavior of P110 steels in CO2-H2S environment with high pressure and high temperature. Materials, 2016, vol. 9, no. 3, p. 200.

Li D.-P., Zhang L., Yandg J.-W., Lu M.-X., Ding J.-H., Liu M.-L. Effect of H2S concentration on the corrosion behavior of pipeline steel under the coexistence of H2S and CO2. International Journal of Minerals, Metallurgy and Materials, 2014, vol. 21, no. 4, pp. 388–394.

Choi Y.S., Nesic S., Ling S. Effect of H2S on the CO2 corrosion of carbon steel in acidic solution. Electrochimica Acta, 2011, vol. 56, no. 4, pp. 1752–1760.

Efron L.N. Metallovedenie v “bolshoy” metallurgii. Trubnye stali [Metal science in “big” metallurgy. Pipe steels]. Moscow, Metallurgizdat Publ., 2012. 696 p.

Shtremel M.A. Inzhener v laboratorii [Engineer in the laboratory]. Moscow, Metallurgiya Publ., 1983. 128 p.

Gorelik S.S., Dobatkin S.V., Kaputkina L.M. Rekristallizatsiya metallov i splavov [Recrystallization of metals and alloys]. Moscow, MISIS Publ., 2005. 432 p.

Stepanov A.A., Lamukhin A.M., Ioffe A.V. Nizkolegirovannaya stal’ [Low alloy steel]. Patent RF no. 2283362, 2004. (In Russian).

Ioffe A.V., Nemtinov A.A., Denisova T.V. Stal’ [Steel]. Patent RF no. 2361958, 2007. (In Russian).

Ioffe A.V., Tetyueva T.V., Denisova T.V. Korroziyno-stoykaya stal’ dlya nasosno-kompressornykh i obsadnykh trub [Corrosion-resistant steel for tubing and casing pipes]. Patent RF no. 2371508, 2008. (In Russian).

Vyboyshchik M.A., Ioffe A.V. The development of steel resistant to carbon dioxide corrosion in oil-producing fluids. Perspektivnye materialy. Togliatti, TGU Publ., 2017. Vol. VI, pp. 115–160.

Tetyueva T.V., Ioffe A.V., Vyboishchik M.A., Knyaz’kin S.A., Trifonova E.A., Zyryanov A.O. Effect of inoculation, microalloying and heat treatment on corrosion resistance and mechanical properties of steel 15Kh5M. Metal Science and Heat Treatment, 2013, vol. 54, no. 9-10, pp. 504–511.

Technical Sciences